... the mixture settings for some fighters are only 100% and 120%.
That happens because that kind of carburetor fitted on that plane does have an automatic mixture control and only for take-off the pilot is allowed to manually enrich mixture above 100%.
More in detail, IL-2 models four kinds of fuel systems as follows:
Inline Suction
Carburetor
Injector
Float carburetor
this, together with provision for a "Mixer Type" which can be:
Generic
Rolls-Royce Automatic
NII Carburetor @ Manifold Pressure Limits
and availability to the pilot of a "command for mixture", allows to model a wide range of fuel systems, combining these various options in the flight model, from full manual control to fully automatic.