Outside of the WarPact, Syria '82, Angola '83 & '87~88, Libya '86, and Iraq '91 are the countries, where it was fielded in wartime situation, during the Cold War.
Hpasp Free SAM Simulator, "Realistic to the Switch" (U-2 over Sverdlovsk, B-52's over Hanoi, F-4 Phantoms over the Sinai, F-16's and the F-117A Stealth bomber over the Balkans.) http://sites.google.com/site/samsimulator1972/home