There is a small fee involved to enable SLI and Crossfire on mobos. So you have to spend a little more to get both on a mobo.
ASUS makes the most mobos of all the manufacturers. Can't go wrong there. I would say next up on the scale would be Gigabyte. EVGA sells mostly reference boards and really has the best service reputation as far as warranty and RMAs there are in the industry. Nothing wrong with Intel, just usually have all overclocking options disabled so if you want to OC, stay away from Intel. MSI makes some good boards, I just don't have much experience with them. I know they make a lot of OEM boards for like HP and eMachines.
The colonel suggests saving money on the PSU. If you are wanting to go with two cards in the future, you should really make sure you get a good name brand PSU in the 800 up watt category as 650W for SLI of Crossfire might work, but I've seen too many issues with PSUs being loaded to the max and causing reboots and data loss.
There are some general rules for building a good overclockable system. Don't try to save money on the mobo and get a good top tier manufacturer like ASUS or Gigabyte. Don't scrimp on memory like buying OEM or no-name. and don't scrimp on the PSU.
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MSI P55-GD65 with i5-750 @ 4.0Ghz vcore 1.370
Xigmatek Balder HS/2 120mm fans, Antec EW PSU EA750 750W
GSKILL Ripjaws 2x4Gb DDR3 1333
One 2Tb Seagate LP, two 1.5Tb LP Seagates
Gigabyte GTX 460 1Gb OC to within an inch of it's life
Lite-On 24X DVD burner, LG 12X Blu-Ray burner
COOLER MASTER Storm Scout
Win 7 Pro 64
Lots of fans spinning with little LED lights blinking
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